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State of the art technology - Continuous casting  calcium fluoride scale inhibition

The challenge

During history of steel production theprocess of continuous casting became moreand more important since the 1960s. Todaymore than 80% of the worldwide steelproduction uses continuous casting. In somecountries, e.g. Germany, the amount isbigger than 95%.

To maximize production output it is essentialto optimize operational and maintenanceflexibility of the caster ongoing. Beneathmachine elements and control systems thisconcerns the secondary cooling as well.

Scheme of continuous caster:

Scheme of continuous caster

Below the mold the slabs have to be cooledby spraying cooling water until its completesolidification.

Crucial for an effective spraying is including:

  • drop velocity
  • drop size
  • water drop fluxIt

It is obvious that clean and free of scale spraynozzles are unalterable for an efficient and precisecooling of the slabs. An improper spray patterncould not only cause cracks but decrease steelquality significantly. Main source for cloggingissues at the spray nozzles is calcium fluoride.

Spray nozzles with initial calcium fluoride scale:

Spray nozzles with initial calcium fluoride scale

The solution

To avoid scaling and clogging Kurita uses specialcrystallization inhibitors. Through the adsorption ofinhibitor molecules on selected crystal faces, achange in the morphology of the developing scalecrystals can reduce the rate of crystallization tonearly zero.

The LD-steel plant of this study uses products ofthe Kurita Polycrin series very successfully.

To determine the best available technique for this system, our R&D centre first evaluated parameters like specific freshwater quality, cooling water circulation and cycle and every relevant facility condition.


During lab test runs the appropriate treatment program and the most efficient Kurita inhibitor were identified, based on a patented blend of organophosphonates and polyacrylates.


During the running application at the plant, it was interesting to show the coherences and relation of product dosing, cycle and scaling tendency. Therefore, the liable parameters were changed systematically as follows:

Conditions:

targetCCM direct cooling water
sampling locationreturn water
temperature40°C
agitating time1 h
scale inhibitorKurita Polycrin
test no.run 1run 2run 3
cycle1,411,752,0
[mg/l]
pH [-]8,358,358,35
calcium hardness102127145
fluoride ion407398
M-alkalinity282350400
suspended solids252252252
Na ion178250302
K ion606060
saturation index (Ca-F)2,563,183,59

 Dosing rate/scale inhibition at various cycles:

The result

The treatment with Kurita Polycrin provided an excellent facility performance. The spray nozzles of the secondary cooling water system were nearly scale free. Very small dosing rates showed very effective scale inhibition. Devices of the mold and bending zones, which have to be cleaned frequently before this kind of treatment, reached up to 3 times longer running periods today.


The exactly defined application, fitted to the specific requests of our partner, minimizes breakdowns and leads to highest possible safety level.


The running times of important parts of the continuous caster machine were extended significantly and the costs for maintenance and production failure were reduced considerably.